Lanthanide-doped NaYF4 nanocrystals in aqueous solution displaying strong up-conversion emission

Autor(en): Schaefer, Helmut
Ptacek, Pavel
Koempe, Karsten
Haase, Markus 
Stichwörter: Chemistry; Chemistry, Physical; ENERGY-TRANSFER; ER3+; Materials Science; Materials Science, Multidisciplinary; PHOSPHORS; QUANTUM DOTS; SIZE; SOLIDS; STATE; TM3+; YB3+
Erscheinungsdatum: 2007
Herausgeber: AMER CHEMICAL SOC
Journal: CHEMISTRY OF MATERIALS
Volumen: 19
Ausgabe: 6
Startseite: 1396
Seitenende: 1400
Zusammenfassung: 
NaYF4:Yb3+,Er3+ nanocrystals showing high colloidal solubility in water have been obtained by treating the nanocrystals with 1-hydroxyethane-1,1-diphosphonic acid (HEDP). HEDP attaches to the surface of the nanoparticles and leads to well-separated particles in aqueous solution as verified by IR spectroscopy and dynamic light scattering measurements. In addition, the surface modification with HEDP increases strongly the up-conversion efficiency of powders and aqueous colloidal solutions of the nanocrystals. These attractive features, above all the hydrophilic nature of the nanoparticles, should make them suitable especially for bio-applications.
ISSN: 08974756
DOI: 10.1021/cm062385b

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