The role of cations in hydrothermal synthesis of nonlinear optical sodium niobate nanocrystals

Autor(en): Kohlenbach, Nico-Dominik
Kijatkin, Christian
Koenig, Matthias
Haase, Markus 
Imlau, Mirco 
Koempe, Karsten
Stichwörter: Chemistry; Chemistry, Multidisciplinary; GENERATION; KNBO3; LATTICE-PARAMETERS; Materials Science; Materials Science, Multidisciplinary; MICROCRYSTALLINE; NANBO3; Nanoscience & Nanotechnology; PHASE-TRANSITIONS; Physics; Physics, Applied; RAMAN-SCATTERING INVESTIGATIONS; Science & Technology - Other Topics; SOLVOTHERMAL SYNTHESIS; STRUCTURAL EVOLUTION; SUBMICROCRYSTALLINE
Erscheinungsdatum: 2020
Herausgeber: ROYAL SOC CHEMISTRY
Journal: NANOSCALE
Volumen: 12
Ausgabe: 37
Startseite: 19223
Seitenende: 19229
Zusammenfassung: 
The usability of the alkali niobates with their ferroelectric and photorefractive properties could be expanded if the development of synthesis methods would allow to obtain small, preferably monodispersed, crystals in the sub-mu m to nanometer regime. Of all the possible synthesis methods, the most reliable is currently hydrothermal synthesis to generate small crystallite sizes of these materials. Although the products of sodium niobate are polydisperse and partially agglomerated, they show a significant SHG signal that is unexpectedly comparable to that of potassium niobate. A view on the hydrothermal synthesis of sodium niobate reveals that the incorporation of cations in the crystalline lattice of the niobium educt plays a part in the formation of the product. The occurrence of distinct different phases, as in the case of potassium niobate, is not observed. Instead, it is shown that a clear assignment of the crystalline phase cannot be made here. This indicates that crystallization of the alkali niobates in hydrothermal synthesis depends on the stoichiometry, the niobium starting material and the cation used.
ISSN: 20403364
DOI: 10.1039/d0nr03840g

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